$ ls $(brew --prefix mysql)/support-files/my-*
/usr/local/opt/mysql/support-files/my-default.cnf
こちらにある内容がデフォルトになる
$ cp $(brew --prefix mysql)/support-files/my-default.cnf /usr/local/etc/my.cnf
$ vi /usr/local/etc/my.cnf
で各種設定を行い
$ mysql.server stop
$ mysql.server start
参考:
http://qiita.com/hkusu/items/cda3e8461e7a46ecf25d
http://stackoverflow.com/questions/7973927/for-homebrew-mysql-installs-wheres-my-cnf