\begin{eqnarray}
\frac{\partial}{\partial \bf{\xi}} \log \left( p(\bf{x}; \bf{\xi})\right)
&=&
\frac{\partial}{\partial \bf{\xi}} \log
\left(
\frac{e^{-E(\bf{x}; \bf{\xi})}}{Z}
\right) \\
&=&
- \frac{\partial}{\partial \bf{\xi}}
E(\bf{x}; \bf{\xi})
- \frac{\partial}{\partial \bf{\xi}} \log(Z) \\
&=&
- \frac{\partial}{\partial \bf{\xi}}
E(\bf{x}; \bf{\xi})
- \frac{\partial}{\partial \bf{\xi}}
\log
\left(
\sum_{\bf{x}} e^{-E(\bf{x}; \bf{\xi})}
\right) \\
&=&
- \frac{\partial}{\partial \bf{\xi}}
E(\bf{x}; \bf{\xi})
- \frac{1}{Z}
\sum_{\bf{x}}
\frac{\partial}{\partial \bf{\xi}} \left(e^{-E(\bf{x}; \bf{\xi})} \right) \\
&=&
- \frac{\partial}{\partial \bf{\xi}}
E(\bf{x}; \bf{\xi})
- \sum_{\bf{x}}
\frac{e^{-E(\bf{x}; \bf{\xi})}}{Z}
\frac{\partial}{\partial \bf{\xi}} \left( -E(\bf{x}; \bf{\xi}) \right) \\
&=&
- \frac{\partial}{\partial \bf{\xi}}
E(\bf{x}; \bf{\xi})
+ \left \langle
\frac{\partial}{\partial \bf{\xi}} E(\bf{x}; \bf{\xi})
\right \rangle_{\bf{x}} \\
\end{eqnarray}